If you have multiple e-mail profiles on your computer and you want Outlook to prompt you to select a specific profile when program starts, you can configure Outlook to do this.
To configure Outlook 2007 and Outlook 2003 to prompt you for a specific e-mail profile, follow these steps:
1. Click Start, and then click Run.
2. Copy and paste (or type) the following command in the Open box and then press ENTER:
control panel
3. If you are in Classic View, double-click Mail. The Mail Setup dialog box opens. Go to step 5.
4. If you are in Category View, under Control Panel, click Switch to Classic View, and then double-click Mail.
5. In the Mail Setup dialog box, click Show Profiles.
6. On the General tab, under When starting Microsoft Office Outlook, use this profile, click Prompt for a profile to be used.
7. Click OK.